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It was the first time that a high-ranking Syrian official signaled that the government was open to talking with Syrian rebels who have taken up weapons against the armed forces. Syria's president, Bashar al-Assad, called in January for talks to resolve the conflict, but appeared to rule out dialogue with Syrians who were armed.

The new statement came as two opposition figures said that the main Syrian opposition leader, Sheik Ahmad Moaz al-Khatib, had already met quietly on at least one recent occasion with a prominent Syrian businessman with close ties to Mr. Assad, apparently in an effort to explore channels for discussion.

Both sides are under pressure from their international backers to explore ways to end the fighting that threatens to destroy Syria and spread conflict beyond its borders.

But Syrian opposition leaders gave conflicting signals on Monday on the future of any talks with members of Mr. Assad's government.

The rebels' top military leader, Gen. Selim Idriss, seemed to harden the opposition's position, ruling out any negotiations until after Mr. Assad steps down — a precondition the Syrian government and its main international backer, Russia, reject. But Sheik Khatib said his offer to talk with members of the government without "blood on their hands" remained on the table, although he criticized what he called the Syrian government's slowness to respond.

Russia declared last week that it would work with the Arab League to bring about direct talks between the government and the rebels, and Syria's foreign minister, Walid al-Moallem, was meeting in Moscow on Monday with his Russian counterpart, Sergey V. Lavrov.

"We are ready for a dialogue with anyone who's willing," Mr. Moallem said ahead of the meetings, Russian news agencies reported. "Even with those who carry arms."

It was unclear whether the Syrian government would ask rebels to lay down arms before such talks. The rebels have said before that they will reject such a precondition.

General Idriss, the leader of the Free Syrian Army, the main rebel fighter group, said that to the contrary, a cessation of violence by the government was "the bottom line" for rebels ahead of any talks. In remarks to Al-Arabyia, a Saudi-backed news Web site, General Idriss also said, "There needs to be a clear decision on the resignation of the head of the criminal gang Bashar Assad, and for those who participated in the killing of the Syrian people to be put on trial."

The main opposition group, the National Coalition of Syrian Revolution and Opposition Forces, led by Sheik Khatib, had long insisted on Mr. Assad's departure as a precondition for talks, but on Jan. 30, Sheik Khatib floated the idea of negotiations with members of the government not directly involved in the bloody crackdown.

On Friday after meetings in Cairo, the coalition adopted a written framework for talks that stopped short of calling for Mr. Assad to step down. It called for Mr. Assad and others involved in the killing to be "held accountable for their crimes" and declaring that they "will not be a part of this political solution."

But many in the coalition remain skeptical of talks with the government and see them as a way for Mr. Assad to buy time, and are frustrated that the rebels are under pressure to compromise amid what they see as insufficient international support.

On Monday, Samir Nachar, a member of the coalition, said that Sheik Khatib had met in the past week with Muhammad Hamsho, a prominent Syrian businessman who is close to Maher al-Assad, the president's brother who leads the army's feared Fourth Division, and a frontman for many Assad family enterprises.

News of the meeting, which surfaced in the London-based pan-Arab newspaper Asharq al-Awsat, prompted a new round of criticism in some opposition quarters of Sheik Khatib. The newspaper quoted Faiek al-Meer, a member of the banned opposition Democratic People's Party, as saying that Sheik Khatib had met with Mr. Hamsho without telling other coalition members.

Mr. Nachar said that Sheik Khatib had briefed him and other coalition members on the recent meeting, which he said had been initiated by Mr. Hamsho.

"Hamsho asked to meet Moaz al-Khatib and the latter agreed," Mr. Nachar said in an interview. "The meeting did take place, yes. Al-Khatib was straightforward about it place but he refrained from going into details."

Mr. Hamsho is one of several Syrian figures on whom the United States Treasury Department has imposed sanctions since Mr. Assad's harsh crackdown on a peaceful protest movement that began in March 2011 and has since evolved into a civil war.

"Muhammad Hamsho earned his fortune through his connections to regime insiders, and during the current unrest, he has cast his lot with Bashar al-Asad, Mahir al-Asad and others responsible for the Syrian government's violence and intimidation against the Syrian people," David S. Cohen, under secretary for terrorism and financial intelligence, said in a statement in August 2011.

Sheik Khatib did not directly address the issue, but posted a message on his personal Facebook page cautioning against rumors.

Sheik Khatib told reporters in Cairo that he had not had any contacts with the Syrian government about potential meetings, and did not immediately respond to the offer from the Syrian foreign minister. He said that he would postpone a planned visit to Moscow "until we see how things develop," The Associated Press reported.

He added, "We are always open to initiatives that stop the killing and destruction but the regime rejected the simplest of humanitarian conditions. We have asked that the regime start by releasing women prisoners and there was no response," he said. "This regime must understand that the Syrian people do not want it anymore."